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Produktbild: Mechanical Properties of Solid Polymers

Mechanical Properties of Solid Polymers

183,99 €

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Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

15.12.2025

Verlag

Wiley

Seitenzahl

464

Maße (L/B/H)

24,6/17,5/2,8 cm

Gewicht

975 g

Auflage

4th edition

Sprache

Englisch

ISBN

978-1-394-20206-5

Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

15.12.2025

Verlag

Wiley

Seitenzahl

464

Maße (L/B/H)

24,6/17,5/2,8 cm

Gewicht

975 g

Auflage

4th edition

Sprache

Englisch

ISBN

978-1-394-20206-5

Herstelleradresse

Libri GmbH
Europaallee 1
36244 Bad Hersfeld
DE

Email: gpsr@libri.de

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  • Produktbild: Mechanical Properties of Solid Polymers

  • Preface xiii

    1 Structure of Polymers 1

    1.1 Chemical Composition 1

    1.2 Physical Structure 9

    References 17

    Further Reading 18

    2 The Mechanical Properties of Polymers: General Considerations 19

    2.1 Objectives 19

    2.2 The Different Types of Mechanical Behaviour 19

    2.3 The Elastic Solid and the Behaviour of Polymers 21

    2.4 Stress and Strain 22

    2.5 The Generalized Hooke's Law 26

    References 29

    3 Finite Strain Elasticity 31

    3.1 The Generalized Definition of Strain 31

    3.2 The Stress Tensor 43

    3.3 The Stress-Strain Relationships 44

    3.4 The Use of a Strain-Energy Function 48

    References 62

    Further Reading 63

    4 Rubber-Like Elasticity 65

    4.1 General Features of Rubber-Like Behaviour 65

    4.2 The Thermodynamics of Deformation 66

    4.3 The Statistical Theory 69

    4.4 Modifications of Simple Molecular Theory 76

    4.5 The Internal Energy Contribution to Rubber Elasticity 85

    4.6 Applications Using Finite Element Modelling 87

    4.7 Conclusions 88

    References 88

    Further Reading 91

    5 Linear Viscoelastic Behaviour 93

    5.1 Viscoelasticity as a Phenomenon 93

    5.2 Mathematical Representation of Linear Viscoelasticity 98

    5.3 Dynamical Mechanical Measurements: The Complex Modulus and Complex Compliance 109

    5.4 The Relationships Between the Complex Moduli and the Stress Relaxation Modulus 114

    5.5 The Relaxation Strength 120

    References 122

    Further Reading 122

    6 The Measurement of Viscoelastic Behaviour 125

    6.1 Creep and Stress Relaxation 125

    6.2 Dynamic Mechanical Thermal Analysis (DMTA) 128

    6.3 Wave-Propagation Methods 128

    References 132

    7 Experimental Studies of Linear Viscoelastic Behaviour as a Function of Frequency and Temperature: Time-Temperature Equivalence 135

    7.1 General Introduction 135

    7.2 Time-Temperature Equivalence and Superposition 141

    7.3 Transition-State Theories 143

    7.4 The Time-Temperature Equivalence of the Glass Transition Viscoelastic Behaviour in Amorphous Polymers and the Williams, Landel and Ferry (WLF) Equation 147

    7.5 Normal-Mode Theories Based on Motion of Isolated Flexible Chains 156

    7.6 The Dynamics of Highly Entangled Polymers 160

    References 163

    8 Anisotropic Mechanical Behaviour 167

    8.1 The Description of Anisotropic Mechanical Behaviour 167

    8.2 Mechanical Anisotropy in Polymers 168

    8.3 Measurement of Elastic Constants 171

    8.4 Development of Mechanical Anisotropy in Oriented Polymers 181

    8.5 Interpretation of Mechanical Anisotropy: General Considerations 188

    8.6 Experimental Studies of Anisotropic Mechanical Behaviour and Their Interpretation 193

    8.7 The Aggregate Model for Chain-Extended Polyethylene and Liquid Crystalline Polymers 208

    8.8 Auxetic Materials: Negative Poisson's Ratio 212

    References 215

    9 Morphology and Structural Effects 223

    9.1 Evolution of Structures Under Tension: Cavitation 223

    9.2 Effects of Stress Field 225

    9.3 One-Dimensional Modelling 229

    9.4 Three-Dimensional Models 235

    References 241

    10 Relaxation Transitions: Experimental Behaviour and Molecular Interpretation 245

    10.1 Amorphous Polymers: An Introduction 245

    10.2 Factors Affecting the Glass Transition in Amorphous and Low Crystallinity Polymers 247

    10.3 Relaxation Transitions in Crystalline Polymers 252

    10.4 Conclusions 265

    References 265

    11 Non-linear Viscoelastic Behaviour 269

    11.1 The Engineering Approach 270

    11.2 The Rheological Approach 273

    References 294

    Further Reading 297

    12 Yielding and Instability in Polymers 299

    12.1 Discussion of the Load-Elongation Curves in Tensile Testing 300

    12.2 Ideal Plastic Behaviour 307

    12.3 Historical Development of Understanding of the Yield Process 317

    12.4 Experimental Evidence for Yield Criteria in Polymers 320

    12.5 The Molecular Interpretations of Yield 325

    12.6 Yield Considered to Relate to the Movement of Dislocations or Disclinations 338

    12.7 The Billon Model 346

    12.8 Multi-axial Deformation: Three-Dimensional Plasticity 347

    12.9 Cold-Drawing, Strain Hardening and the True Stress-Strain Curve 350

    12.10 Shear Bands 358

    12.11 Physical Considerations Behind Viscoplastic Modelling 360

    References 363

    Further Reading 371

    13 Fracture 373

    13.1 Definition of Tough and Brittle Behaviour in Polymers 373

    13.2 Principles of Brittle Fracture of Polymers 374

    13.3 Finite Geometries 379

    13.4 Elastic Anisotropy 381

    13.5 Controlled Fracture in Brittle Polymers 382

    13.6 Crazing in Glassy Polymers 384

    13.7 Controlled Fracture in Tough Polymers 393

    13.8 Factors Influencing Brittle-Ductile Behaviour: Brittle-Ductile Transitions 403

    13.9 The Impact Strength of Polymers 410

    13.10 The Tensile Strength and Tearing of Polymers in the Rubbery State 417

    13.11 Time and Temperature Effects 420

    13.12 Fatigue in Polymers 424

    References 429

    Further Reading 438

    Index 439